Sorry, I cannot start the app, when downloading and running the defender takes care and removes the “unsafe” unity dlls. In general running Unity App work when I install with the itch.io app - your app cannot be installed inside the itch app
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I didn't know itch.io could be installed as an app. I tried downloading it in this mode and I can still run the game. You probably have some defender setting that protects you from certain types of files. You should try changing those settings if you want to try to play the game, also because I have seen that more than half of the jam games have the same format and file types. Thanks for the report.