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I think having more saturated colors to help your objects stand out is a great idea!  I can see them very clearly and your overall design is appealing as well. 
Personally I would try the terrain palette with the UI first and see if I liked it.  Sometimes high saturation can be hard on the eyes, I think. 
I like what you have so far and I think you're on the right track!   Wishing you good luck with your game!  :)