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If you've completed Bernice's route by the time Lucifer declares you the Messiah, Sylos will be fully available to buy condoms. The other way to get condoms is to break into the school lockers, some of which have a small chance of dropping condoms.

Thank you I did Bernice quest and the shop unlocked

Well I've done just about every quest and I still can't just buy one  alice is the only person that has a current objective 

you may be missing stuff from wandering around town then, but pretty sure getting announced as the messiah is the only thing needed to buy condoms from the drug store.