I believe the witch in the swamp gives you the recipe, although the way she tells it to you is rather cryptic. The recipe is: Green Pulp, Mushroom, Nothing, Mushroom, Green Pulp.
loweffortusername
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A member registered Jan 16, 2021
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The recipe for the Restrain Potion is Red Berry, Nut, Nothing, Nut, Red Berry.
Strong Restrain Potion is Red Pulp, Nut, Earth Moss, Nut, Red Pulp (not sure which one you need).
Either way, once you make a potion, it should unlock the recipe for it if you don't already have it. It will also make a quick shortcut for it once you've successfully made the potion 4 times.
You need to get the 2nd heart with him. To get it, you need to talk with Rose about Arion, and she'll suggest you give him a flower (she sells you one). After you give him the flower, come back in a day or two and Arion will give you another flower in return. Respond positively, and it'll unlock the 2nd heart.