ohh, i was referring the star quarterback, the captain of the football team?
It basically depends on their part in the story. Romance isn't possible (yet) with the quarterback, but you can have a D/s relationship with the RM/RMP since it's in their storyline. Some special NPCs (the rich kid, QuickieBurger owner, etc.), even if they're single, also aren't romanceable to male protagonists because they're straight.