Zhokhar's romance route doesn't become available until reaching Spiceport City. If you want to pursue a relationship with him, stay single until then.
Eddio
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...No, you can't unlock Zhokhar's scenes while pursuing a romantic relationship with Mac. That defeats the whole point of a romance route.
If you want to start unlocking Zhokhar's Spiceport scenes, Killigan must be single when going into Spiceport City. You can easily do this by skipping to the beginning of Spiceport in a new game.
"I wanted to know if these characters will be Killigan's future partners"
Yes, they will be. As the text says: They will become romance options as the game progresses, they are not available as romance partners from the start.
I am not fluent in Portuguese, so here is that response again through Google Translate: Eles se tornarão opções de romance à medida que o jogo avança; eles não estão disponíveis como parceiros de romance desde o início.